Chemistry is an experimental science, Application In Synthesis of 2-Chloro-5-hydroxypyrimidine, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 4983-28-2, Name is 2-Chloro-5-hydroxypyrimidine, molecular formula is C4H3ClN2O, belongs to pyrimidines compound. In a document, author is Behera, Prafulla Kumar.
Gold(I) and gold(III) complexes supported by a pyrazine/pyrimidine wingtip N-heterocyclic carbene: Synthesis, structure and DFT studies
Starting from pyrazine and pyrimidine functionalized N-heterocyclic carbene (NHC) proligand 1-(2-Pyrazinyl)-3(methyl) imidazolium chloride (1.HCl), 1-(2-Pyrimidyl)-3(methyl) imidazolium chloride (2.HCl), four novel gold complexes [Au(1)Cl], (1a); [Au(1)Cl-3], (1b), [Au(2)Cl], (2a) and [Au(2)Cl-3] (2b) were synthesized and characterized using NMR spectroscopic techniques and elemental analysis. Additionally, the solid state structures of 1a & 2b were elucidated using single crystal X-ray diffraction analysis, which revealed that in 1a, the carbene nucleus and the chloride ion bound to Au(I) nearly linear having C-Au-Cl bond angle 178.84 degrees. Where as in 2b, the carbene nucleus and the chloride ion bound to the Au(III) adopts the square planar geometry surrounding Au(III). A series of DFT calculations were also performed to gain further insight into the respective structures of the complexes to relate the crystallographic parameters and electronic distribution. (C) 2020 Published by Elsevier B.V.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 4983-28-2. Application In Synthesis of 2-Chloro-5-hydroxypyrimidine.
Reference:
Pyrimidine | C4H4N2 – PubChem,
,Pyrimidine – Wikipedia