The pyrimidine ring system has wide occurrence in nature as substituted and ring fused compounds and derivatives, 1722-12-9, formula is C4H3ClN2, Name is 2-Chloropyrimidine. including the nucleotides cytosine, thymine and uracil, thiamine (vitamin B1) and alloxan. Product Details of C4H3ClN2.
Dong, Lefeng;Feng, Tingting;Xiong, Dongdong;Xu, Zhiping;Cheng, Jiagao;Xu, Xiaoyong;Shao, Xusheng;Li, Zhong research published 《 Copper(II)-Catalyzed Direct C-H Trifluoroethylation of Heteroarenes》, the research content is summarized as follows. Herein, an efficient method for the copper-catalyzed direct trifluoroethylation of heteroarenes such as 5-(pyrimidin-2-yl)-5H-[1,3]dioxolo[4,5-f]indole, 2-(5-methylfuran-2-yl)pyrimidine, 2-(5-methylthiophen-2-yl)pyrimidine, etc. was reported. The reaction exhibited good compatibility to various substrates, and the desired products such as 5-(pyrimidin-2-yl)-6-(2,2,2-trifluoroethyl)-5H-[1,3]dioxolo[4,5-f]indole, 2-(5-methyl-3-(2,2,2-trifluoroethyl)furan-2-yl/thiophen-2-yl)pyrimidine, etc. were obtained in good yields. Preliminary mechanistic investigations indicates that the trifluoroethyl radical is involved in the catalytic circle.
1722-12-9, 2-Chloropyrimidine is a monochlorinated pyrimidine with plant growth regulating activity. Chloropyrimidine is a useful reagent in the preparation of antivirals and other biologically active compounds.
2-Chloropyrimidine undergoes cobalt-catalyzed cross-coupling reaction with aryl halides.
2-Chloropyrimidine is a molecule that can be synthesized by the oxidation of pyrimidine with hydrogen peroxide and hydrochloric acid. The reaction proceeds through an electrochemical process in which the oxidation catalyst is a platinum electrode. This reaction is catalyzed by the nucleophilic attack of malonic acid on the chloropyrimidine at the methylene group. This efficient method for making 2-chloropyrimidine has been applied to synthesize aryl halides, including phenyl chloropyrimidine and pyridyl chloropyrimidine, from their corresponding chloride and bromide precursors. The fluorescence properties of 2-chloropyrimidine have been studied in coordination chemistry, where it forms complexes with metal ions such as Mn2+. In this study, it was found that adsorption mechanisms are dependent on molecular size, charge density, kinetic energy, and adsorbent surface area., Product Details of C4H3ClN2
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia